Reactions and synthesis
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Research
Propeller molecule acts as chirality sensor for solvents
Unusual chiral induction phenomenon observed in a molecular system
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Research
Mercury poisoning test gets it wrong for palladium catalysts
The 100-year-old mercury drop test to distinguishing between homogeneous and heterogeneous catalyst is not as reliable as chemists thought
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Research
Bond-breaking reaction chops up wood chemical
Reaction that splits biphenols in two could convert lignin into useful chemicals
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Research
Waste vegetable oils turned into chemicals for drugs and plastics
Dual catalytic system converts complex carboxylic acids into terminal alkenes
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Research
First four-twist aromatic molecule made
A di-palladium complex with 54 π electrons is the first quadruply twisted aromatic molecule
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Research
Chemical pulse animates lifelike colour-changing system
Purple–pink oscillation could herald strong and stimuli-responsive materials
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Research
CryoEM method offers organic analysis certainty
MicroED technique gives rapid, unambiguous structure determination with small, amorphous samples
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Research
First persistent monosubstituted carbene created
Clever structural design enables room-temperature isolation of highly reactive molecule
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Research
Molecular archery allows chemists to see how bonds form
Scientists shoot the world’s smallest projectiles – individual molecules – and use them to study how reactions happen
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Research
Chunky catalyst mimics enzyme to tackle tough reactions
Tricky Diels–Alder reactions or Mukaiyama aldol additions – a bulky chiral catalyst can do them all by squeezing substrates into its chiral pocket