Palladium catalyst voyage prompts carbon–carbon bond formation rethink

An image showing the localization of reactant and product emission bursts

Source: © Paolo Costa et al/Springer Nature Limited 2020

Suzuki–Miyaura cross-coupling catalyst atoms leach away but then return to their supports

Ingenious fluorescence microscopy experiments have revealed palladium atoms’ liberated behaviour, helping answer unresolved questions about an important process for forming bonds between carbon atoms. The Suzuki–Miyaura cross-coupling won Akira Suzuki a Nobel prize in chemistry in 2010, but there has been debate about whether solid palladium catalysts are dissolving or not.