Smart glass for energy efficient windows

Scientists from China and the US have produced glass that responds to its environmental temperature, making it a promising material for energy efficient windows. On cold days, the windows would prevent heat escaping and on hot days, the windows would reflect infrared radiation, keeping the room inside cool. 

Vanadium dioxide (VO₂) has long been recognised as a potential candidate material for making ’smart windows’ because it can change from a transparent semiconductive state at low temperatures, allowing infrared radiation through, to an opaque metallic state at high temperatures, while still allowing visible light to get through. VO₂ has its drawbacks, however: it’s not a very good insulator and can only be made at very high temperatures of 420-500?C.

Zhong Lin Wang at the Georgia Institute of Technology, Atlanta, and co-workers at the   Shanghai Institute of Ceramics Chinese Academy of Sciences and the Graduate University of Chinese Academy of Sciences in Beijing, have created a system with improved insulating ability by combining a layer of VO₂ with a transparent fluorine-doped tin oxide (FTO) layer coated on glass. As an added benefit, the  FTO layer enhances the crystallinity of the VO₂ film - an important factor for improving the material’s performance and reducing its cost - and lowers the synthesis temperature to 390?C.

’Buildings and maintaining man-made structures use 30-40 per cent of the primary energy supply, mainly for heating, cooling, ventilation and lighting. Effective control of the energy exchange between the interior and exterior of buildings through windowpanes is a key area in saving energy,’ says Yanfeng Gao, one of the researchers. ’We conducted this research to create a film that can combine the functions of low emissivity and thermochromic coatings.’

Materials expert Seeram Ramakrishna, from the National University of Singapore, sees advantages to the group’s approach. However, he also feels that improvements could be made to optimise the system. The work ’doesn’t attempt to bring down the transition temperature of VO₂  to room temperature, which would be desirable if it is to have practical technological applications,’ he says.   

Gao now hopes to realise his dream of seeing the smart windows go into mass production.

Heather Montgomery

Link to journal article

Solution-based fabrication of vanadium dioxide on F:SnO₂ substrates with largely enhanced thermochromism and low-emissivity for energy-saving applicationsZongtao Zhang, Yanfeng Gao, Hongjie Luo, Litao Kang, Zhang Chen, Jing Du, Minoru Kanehira, Yuzhi Zhang and Zhong Lin Wang,?Energy Environ. Sci., 2011, 4, 4290DOI:10.1039/c1ee02092g