Propulsion induced by a surface tension gradient is known as Marangoni propulsion. It’s used in nature by small creatures such as Microvelia (small aquatic insects) to give a burst of speed to escape predators. In man-made devices, the Marangoni effect has been used to power small ‘camphor boats’ and ‘soap boats’; however, these systems normally offer only short term propulsion or require the boat to be confined to specific channels.
To develop a longer-term propulsion system, the team led by Robin Ras at Aalto University, Finland, created a boat from a lightweight membrane made from a nanocellulose aerogel. The membrane is impermeable to water (and oil) but it allows the gaseous surfactants to pass through it. The team used ethanol as the fuel to power a boat floating on water.
Housed in a reservoir at the rear of the boat, a few drops of ethanol are placed on a tissue. As the ethanol evaporates, it diffuses through the membrane at the rear of the boat and lowers the surface tension of the water. This creates the surface tension gradient that drives the boat forward. The boat is not steered so it typically travels in a circular route. Once the boat has passed, the ethanol at the water surface evaporates, returning the surface tension to normal. Modifying the surface tension only requires a small amount of surfactant.
‘The boat ran for over 54 minutes on only 25 microlitres of fuel,’ says Ras. ‘It’s very fuel efficient while cruising at a speed of 2cm s-1,’ he adds. To demonstrate the generality of their approach, the team showed they could also use pentane to power a boat floating on paraffin oil.
‘This is a beautiful illustration of exciting soft matter research. The researchers combine innovative materials science with fundamental surface science to construct a novel self-propelling floating device that is much more controllable and versatile than any similar device suggested before,’ says Lennart Piculell, an expert in physical chemistry at Lund University, Sweden. ‘I don't see any immediate applications, but the concept is simple and can be applied to even smaller devices.’
- H Jin et al, Chem. Sci., 2012, DOI: 10.1039/c2sc20355c