Transient quantum fluctuations tune polymer self-assembly

Chemists use to the universe’s random electromagnetic fluctuations to profoundly change a compound’s supramolecular organisation

Trapping a polymer in a tiny dark space between two mirrors is all it takes to profoundly change the way it self-assembles – forming flakes instead of the usual fibres. The tiny mirrored box provides so-called vibrational strong coupling between molecules and the vacuum field, the boiling quantum mechanical soup that fills the universe with transient photons and other particles.