Laura Smith
- Research
N-heterocyclic carbene ligands bulk up to better stabilise metal catalysts
New family of molecules has highest steric volume reported to date for N-aliphatic NHC ligands
- Research
Newly discovered marine compound is in a super-carbon-chain league of its own
Isolated from algae, Benthol A has 35 stereocentres
- Research
Computational study finds fluorine in flatland
Proposed planar clusters contain fluorine atoms and group 13 elements
- Research
Mechanism maps predict chemoselectivity of NHC-catalysed transformations
Product forecasts from energy barrier calculations will help guide organocatalytic reactions
- Research
Method decorates cubane with multiple aromatic groups
Di-, tri- and tetra-arylcubanes created by directed ortho-C–H metalation and palladium-catalysed cross-coupling
- Research
Total synthesis of unnatural enantiomer renews interest in quinine
Scientists hope their strategy will invigorate cinchona alkaloid-mimic catalysis
- Research
Surprising radical mechanisms of antioxidant polysulfides
Tetrasulfide prevents oxidation of petroleum products through radical reactions
- Research
Light-activated chirality switch directs enantiomeric excess
Photoexcitation can transform a racemic ligand into one of its enantiomers