All Organic chemistry articles – Page 10
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Research
Chemists reconsider the impact of through-space effects
Through-space electrostatic effects are shown to be dominant in certain radical reactions, where previously through-bond interactions were thought to determine reaction rate
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Research
Supramolecular cage unlocks mild aldehyde reduction strategy
Computational analysis reveals how encapsulation stabilises protonated oxocarbenium ion of furfural, which makes the carbonyl moiety easier to reduce
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Opinion
The active uses of an inert gas
Meeting the many demands for nitrogen in chemical plants requires a fascinating piece of equipment
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Research
Plasmon-assisted click reaction reverses typical relationship between temperature and rate
Decrease in temperature seems to extend lifetime of plasma-induced excited states, which increases probability of reaction occurring
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Research
Programmed cyclodextrin synthesis picks out specific molecule from 117,655 possibilities
Thioacetate orienting group allows for fine-tuned cyclodextrin functionalisation
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Opinion
Five lessons from the career journey of an accidental chemist
Tip and tricks from dilutions to the excellent properties of lab floors
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Research
Neural network based on autocatalytic reaction performs image classification
Click reaction between small organic molecules used to execute a computing task
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Research
Warped nanographene at odds with aromaticity
Scientists discover a π-electron circuit with an odd number of electrons in a polycyclic system
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Research
Coordinative bonding to carbon more nuanced than first thought
New insights from valence bond theory enhance understanding of bonding in carbones
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Research
Double bond metathesis extended to germanium compounds
Partner swapping reaction carried out with digermene compounds, with no need for a catalyst
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Research
Electrochemistry enables new, greener route to aromatic sulfonamides
One-step, metal-free, scalable route synthesises key functional group in drug discovery
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Opinion
Space, energy and synthetic half-reactions
Matching driving forces with intermediates to predict new chemistry
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Research
Amine might end palladium’s reign over classic cross coupling reaction
Suzuki reaction now comes in an organocatalysed format
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Research
Nitrogen radical chemistry sees the light
Daniele Leonori explains how his group is taking inspiration from 30-year-old chemistry to devise shorter syntheses for bioactive compounds
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Research
Electric fields flick the quantum-tunnelling switch in cold reactions
Reaction kinetics affected by direction of external electric field under cryogenic conditions
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Opinion
Bert Meijer: ‘I'm in love with molecules’
The pioneering organic chemist discusses the rewards of working with young people and the role of chemistry in fighting Covid-19
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Research
DFT boosts machine-learning models of nucleophilic aromatic substitution reactions
Best of both worlds for computational organic chemistry predictions
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Research
Mechanochemistry makes ammonia under mild conditions
Ball-milling process could reduce energy consumption associated with key fertiliser feedstock