Organic chemistry – Page 5
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BusinessPan-cancer approval shows huge potential for antibody–drug conjugates
Enhertu gains approval based on gene expression rather than tumour location
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ResearchPorous organic ‘cage of cages’ crystalline structure predicted by computational modelling
Organic cages have been used as precursors to synthesise higher order porous structures, adding to their functionality while the ability to solution process them is retained.
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Research‘Mechanochemistry strikes again’ – this time for deoxygenating phosphine oxides
Mechanochemical process works in 30 minutes under air to regenerate phosphine reagents
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OpinionLab automation gives me more time at the top of the mountain
Getting back to the bench reminds Derek Lowe how much has changed in 40 years
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FeatureIlluminating antiaromaticity
Aromaticity’s dark alter-ego is ready to emerge into the sunlight. James Mitchell Crow talks to the scientists trying to exploit the instability
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ArticleWater microdroplet chemistry enables catalyst-free Diels–Alder reaction
‘Quasi-benzyne’ radical drives exotic reactivity
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ResearchCould mechanochemistry have saved Abbott Laboratories $250 million?
Ball milling solves problem of disappearing ritonavir polymorph
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ResearchTelling left from right: chirality detection faces up to its weaknesses
New solutions are being found to an enduring problem in chemistry
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ResearchFirst mirror-image cyclodextrins come together ‘like Lego’
L-enantiomers could be more stable than their existing, more common, forms
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ResearchCrystalline cages create unusual ‘touchless’ sensors
Researchers connect chemistry and engineering to create touch-free buttons based on the detection of the skin’s water
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ResearchCross-coupling technique cracks open alcohols for chemical synthesis
A new alcohol–alcohol cross coupling reaction could become a powerful new tool for synthetic chemists
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ResearchDIY recycling protocol could save organoiridium waste from incinerators
‘A very good solution to solve a niche problem’
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Research3D-printed capsules enhance speed and safety of synthetic chemistry
Encapsulated reagents allow chemists to ditch their Schlenk line to synthesise ferrocene
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ResearchEnergetically unfavourable Diels-Alder reaction driven by chemical fuel
Carbodiimide fuel powers rare, thermodynamically unpromising reaction between diene and dienophile
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OpinionHarnessing biodiversity through natural products research in the Philippines
Collaborative projects aim to produce cheaper and more effective medicines
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ResearchPorphyrin ribbons transport charge with no resistance
Molecules could form the basis of ‘perfectly transmissive’ molecular wires
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ResearchBad habits obscuring thermodynamic reality of photocatalytic reactions
Dubious assumptions and contentious nomenclature muddying the literature
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ResearchSodium lumps, glucose and mechanochemistry behind ammonia-free Birch reduction
Protocol solves ‘malleability problem’ of activating alkali metals like sodium
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ResearchEnzyme engineering makes blue denim greener
Environmentally friendlier alternative to indigo dye can now be made at a competitive price