All Organic chemistry articles – Page 5
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ResearchRobot chemist snaps 3D building blocks together like Lego to make complex molecules
Automated synthesiser uses a new class of boronates that are a thousand times more stable than those previously used
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Research
Atom-swapping reaction sequence turns cyclic diarylmethanes into diarylethers
Strategy that stitches three different reactions together could be useful for making pharmaceutical intermediates
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Research
Curie temperature high makes organic ferroelectric pair stand out
Homochiral organic ferroelectrics get set to upgrade smart and medical devices
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Opinion
A transition metal handyman
Using nickel templating to promote a large molecule for organic electronics
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Research
Engineered enzyme speeds up sedate organic reaction
Biochemical optimisation applied to the Morita–Hillman–Baylis reaction
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Feature
Wiring up organic synthesis
James Mitchell Crow talks to the organic chemists using electrochemistry to add or remove electrons to their molecules at the flick of a switch
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Research
40-year-old mystery of why some molecules break all cyclisation rules has been solved
Molecules that blatantly violate Woodward–Hoffmann rules could lead to general theory of cyclisation in polar compounds
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News
Chemistry Nobel laureate Robert Grubbs dies at 79
US chemist shared 2005 prize for his role in developing the metathesis method in organic synthesis
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News
The curious incident of the catalytic amine that never was
A series of unfortunate events and a missed control experiment meant palladium sneaked its way into a supposedly amine-catalysed reaction
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Research
Diels-Alder reaction directly observed under the microscope
Simple ring-forming reaction followed on a surface for the first time using scanning probe microscopy
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Research
Record-breaking hexagon made out of fused aromatic rings
90 rings form the largest structure of its kind ever made
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Research
Dearomatisation, but without nasty reagents
New Birch reduction protocol creates solvated electrons without the dangerous combination of liquid ammonia and alkali metal
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Research
Are organic chemists discovering fewer reactions than they were decades ago?
Analysis of millions of transformations reveals reliance on popular methods – and the rise of complex reactions
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Research
Plasma-based approach leads to more reactive oxygen donors for alkene epoxidation
Yield of epoxidation reaction increased, and waste reduced, by using CO2-derived atomic oxygen and plasma-based conditions
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Research
Cooking oils work as solvents for metal-catalysed reactions
Suzuki–Miyaura, Hiyama, Stille, Sonogashira and Heck cross-couplings shown to proceed with quantitative yields in certain vegetable oils, fish oil, butter and waxes
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Feature
How organocatalysis won the Nobel prize
Jamie Durrani tells the story of how two young upstarts, Ben List and David MacMillan, created a whole new field of catalysis
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Research
Exploiting evolution to explore chemical space shows promise for drug discovery
Using molecular trees – similar to family trees – chemists could predict how products will evolve to make new molecules
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Research
Möbius metallacycles show their aromaticity with textbook reactivity
First electrophilic aromatic substitution reactions with unusual molecules
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Research
Explainer: why has asymmetric organocatalysis won the chemistry Nobel prize?
In a rather unexpected move by the Nobel committee, this year’s prize in chemistry has been awarded to Benjamin List and David MacMillan
