Organic chemistry – Page 8
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Research
Charge-transfer interactions during C–H activation directly observed
New insights could guide the design of better catalysts
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Research
Identifying single atoms with x-ray specificity
Combining synchrotron x-rays with scanning tunnelling microscopy gives atomic resolution
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Opinion
Margaret Faul: ‘Stand for what you think is right’
The pharmaceutical executive on why chemistry clicked for her, and life as a female organic chemist in the drug industry
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News
New results vindicate suspect 63-year-old claim on synthesis of first catenane
Researchers hoping to debunk Edel Wasserman’s doubted claims of the first interlinked rings end up supporting them
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Research
N-heterocyclic carbene ligands bulk up to better stabilise metal catalysts
New family of molecules has highest steric volume reported to date for N-aliphatic NHC ligands
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Opinion
Boosting cubane synthesis with photosensitizers
Leaping to a greener approach for cubane synthesis
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Webinar
Poisonous tales with author Hilary Hamnett
Hear from author Hilary Hamnett about her new book Poisonous tales: a forensic examination of poisons in fiction
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Research
Benzene’s forgotten isomer takes centre stage in organic synthesis
1,2,3-cyclohexatriene proves to be an unexpected hit as a reagent in a wide range of reactions
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Research
Electrophotocatalysis widens the scope of carbonyl olefination
New approach avoids the strong bases associated with the Wittig reaction, supporting a wider range of starting materials
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Opinion
Organic chemists should place their trust in machine learning’s black box
Submitting to the higher power of abstraction can strengthen our insights
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Feature
The messy chemistry that led to life
To understand how chemistry became biology, some chemists are eschewing simple reactions to study complex systems with many reactants and products. Rachel Brazil peers through the tangle
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Research
Boron-doped olympicenes are surprisingly stable
By possessing useful electronic properties, boraolympicenes could have potential applications in organic electronics
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Research
Extraordinary crystal structure displays abiotic foldamer with unprecedented complexity
Four aromatic oligoamide helix-turn-helix units assemble in organic solvent into an abiotic architecture with quaternary-like structure
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Research
Soapbark tree’s biosynthetic pathway for vaccine adjuvant saponins
Researchers use genome mining and bioengineering techniques to map out route
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Research
Skeletal editing provides a simple route to access isoquinolines
Direct nitrogen atom insertion into a broad range of indenes and cyclopentadienes
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Feature
Editing the structure of molecules
Nina Notman meets the chemists expanding the toolbox of reactions capable of adding, deleting and switching single atoms in rings at the heart of organic molecules
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Research
‘Dynamic bonds’ reshape the rules of aromaticity and chirality
Discoveries could contribute to new understanding of organic chemistry, triggering applications in catalysis and materials science
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Research
Harvesting water from the air with organic crystals
Discovery could lead to novel technologies for fighting water scarcity
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Research
Water works as medium for reactions that reduce carboxylic acids
Catalytic system works on a wide range of acid substrates and doesn’t require precious metals or air and moisture intolerant reagents
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Research
AI identifies molecules from their featureless visible spectrum
Forget about trying to interpret peaks and let machine learning identify organic compounds from their entirely smooth visible spectrum