Organic chemistry – Page 9
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OpinionAn idea that clicked
Bioorthogonal reactions – doing chemistry inside living cells without blasting everything in sight – are no mean feat
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OpinionCarolyn Bertozzi: ‘Shooting hoops is very meditative’
The celebrated chemical biologist who dreamed of being a rock star before inventing the field of bioorthogonal chemistry
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FeatureThe bioorthogonal revolution
A set of reactions operating silently inside live cells or whole animals are lighting up chemical biology and inspiring new medicines, James Mitchell Crow finds
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ResearchNew family of hollow molecules separates troublesome hydrocarbon mixtures
Meet the cagearenes – 3D frameworks made from aromatic building blocks and methylene groups
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ResearchIt’s not enough to be 3D and aromatic to be 3D aromatic
Misusing the term 3D aromaticity could put chemists on a slippery slope where the concept loses meaning
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ResearchBottleable but reactive carbocations are powerful hydride abstractors
Fluorinated trityl cations outperform trityl for hydride abstraction reactions
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FeatureLife’s chemistry goes through the looking glass
Chemists were taught that natural systems only use L-amino acids. Andy Extance finds out just how wrong that is proving
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OpinionExit strategy
Overcoming a major setback showed Derek Lowe could make it through graduate school
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ResearchSpotlight shone on sped up photochemical reactions in droplets
Light can produce ‘hot spots’ in aerosols that supercharge reaction rates
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ResearchAutomated carbon-13 NMR structure validation program highlights errors atom-by-atom
Introducing a new measure to quantify molecular structural uncertainty
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ResearchMolecular ratchet made from only 26 atoms rotates in one direction
Chiral fuel drives molecular machine’s rotation, mimicking fundamental biological processes
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OpinionBuilding data systems to break down research silos
Shared schemas could make it a lot easier for researchers to cross discipline boundaries
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ResearchLight-driven molecular motor made from entirely renewable resources
Green synthetic strategy leads to first light-driven molecular motor from wood biomass
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ResearchMicroscopy unveils piece-by-piece formation of 2D covalent polymers
New results provide ‘fundamental insights’ on the growth of covalent organic framework monolayers
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ResearchFully nitrated benzene sets explosive record
Nitro-nitroaminobenzene is the organic compound with the largest detonation energy release yet
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ResearchSwitching molecular self-assembly on and off with electricity
New approach uses electrons to catalyse molecular recognition, giving chemists precise control over the process
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ResearchThis computational chemist is experimentalists’ secret weapon in the hunt for new materials
Kim Jelfs discusses how software development feeds – and needs – collaboration
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ResearchStudy finds Goldilocks organoborane catalysts for fluorination
Tuning fluoride ion affinity opens a window for organoborane phase transfer catalysis in nucleophilic fluorination reactions
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