All Metathesis articles
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Research
‘Transformative’ carbonyl cross-metathesis used to synthesise alkenes
Two new catalytic methods can produce a broad range of Z- and E-alkenes with remarkable cross-selectivity, paving the way for more efficient organic syntheses
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Article
Catalysing change in sustainable chemical synthesis
New innovations in a classic concept are making industrial processes greener
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Research
Double bond metathesis extended to germanium compounds
Partner swapping reaction carried out with digermene compounds, with no need for a catalyst
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Research
NMR findings suggest solution to enhanced diffusion dispute
Energy release rate may solve the puzzle of why the phenomenon is seen in some systems but not others
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Article
Metathesis enables everyday innovation
For process chemists, simple solutions to complex problems are crucial. Metathesis is a cost-effective, reliable and scalable tool that enables innovation
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Article
Creating carbon–carbon bonds via transition metal catalysis
Cross-coupling and metathesis reactions are powerful ways of making carbon–carbon bonds, the crucial links behind most organic compounds
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Research
Walking radicals relocate double bonds
Nickel-guided radicals walk along carbon chains to make E-alkenes from terminal alkenes
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Article
Metathesis: around the catalytic cycle
Three Umicore scientists discuss the advantages that metathesis can bring to a variety of industries
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Article
Metathesis: the green method of chemical synthesis
Getting the most out of your reactions is a crucial part of green chemistry. The bond-forming prowess of metathesis catalysts can help
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Article
In conversation with Robert Grubbs, Nobel laureate
Following the recent acquisition of the world-leading Materia catalyst business by Umicore, we’ve been granted an exclusive interview with Robert Grubbs, chemistry Nobel laureate and co-founder of Materia.
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Research
Unusual metathesis catalyst holds stereoselectivity promise
Molybdenum catalyst can make Z -trifluoromethyl-substituted olefins useful for pharmaceuticals, agrochemicals and materials
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News
Wax pills for safe and simple olefin metathesis hit the market
Capsules preserve air-sensitive chemicals and forego need for glove boxes
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Podcast
Grubbs catalyst
Nina Notman describes the dance of olefin metathesis, and how the tempo is set by Grubbs’ catalysts
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Feature
Three share prize for metathesis work
The discoveries made by this year's Nobel laureates have had a great impact on new drug developments, polymeric materials and industrial syntheses. Karen Harries-Rees reports.