Macrocyclic NHC ligands serve up trio of new actinide sandwich complexes

Actinide sandwich 3D image

Source: © Royal Society of Chemistry

Delocalised, anionic macrocyclic NHCs with unusually strongly σ-donation set to expand suite of stable organometallic complexes with f block cations

Researchers in the US have synthesised the first macrocyclic -heterocylic carbene (NHC) complexes to incorporate elements from the f block and investigated their unusual electronic structures.