All Aromaticity articles
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Research
Increase in aromaticity drives metallaaromatic ring contraction
Acid-promoted ring contraction reaction reshapes an osmaindenol into an osmapentalene
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Research
‘Dynamic bonds’ reshape the rules of aromaticity and chirality
Discoveries could contribute to new understanding of organic chemistry, triggering applications in catalysis and materials science
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Research
It’s not enough to be 3D and aromatic to be 3D aromatic
Misusing the term 3D aromaticity could put chemists on a slippery slope where the concept loses meaning
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Research
This metal triangle seems to defy definition – is it aromatic or not?
Discussion around thorium ring’s aromaticity has chemists questioning if we should stop calling metal clusters aromatic
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Research
Infinity shaped molecule displays unexpected aromaticity
New calculations uncover deeper understanding of the electron delocalisation behaviour in an unusual twisted polyarene
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Research
Bond current graphs offer deeper insights into aromaticity for non-experts
Researchers combine cheap calculations with visual bond-current graphs to give easily interpretable representations of aromaticity in polycyclic compounds
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Research
Double aromaticity puts a hex on gallium
Planar hexacoordinate cluster isn’t stable when other group 13 elements replace gallium
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Research
Möbius metallacycles show their aromaticity with textbook reactivity
First electrophilic aromatic substitution reactions with unusual molecules
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Research
Actinide aromaticity defies predictions
First σ-aromatic thorium cluster extends σ aromaticity to periodic table’s heaviest elements
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Feature
The search for the grand unification of aromaticity
Researchers have been trying to find a full definition of aromaticity for almost two centuries, and yet keep discovering new types
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Research
More metallomimetic chemistry from boron
One boron atom bonds like a transition metal in two different ways
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Research
Warped nanographene at odds with aromaticity
Scientists discover a π-electron circuit with an odd number of electrons in a polycyclic system
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Research
Heavy-metal cluster sets size record for metal aromaticity
12 bismuth ring creates ‘substantial’ π aromaticity with only two aromatic electrons
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Research
Trinuclear complex is a rare example of bottled double aromaticity
First report of a system containing a ruthenium atom that takes part in two different types of aromaticity simultaneously
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Research
Baird’s rule of aromaticity extended to all-metal systems
Aromaticity concept can help scientists understand the properties of metal clusters
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Research
Magnetic shielding maps reveal molecules’ aromaticity
Computational method is intuitive way to visualise Clar’s rule in polycyclic aromatic hydrocarbons
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Research
Introducing the tubulararenes, a new class of strained aromatic compounds
Electroactive container molecules built from the bottom-up
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Research
Uranium and thorium make their debut in dual aromatic–antiaromatic molecule
First two metallabiphenylene compounds synthesised
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Research
Four-leaf clover molecule with metal centre is first in a new family of aromatics
First molecule made of four fused aromatic rings around an osmium atom