Observing the life and death of a single excited-state molecule

An image showing three schematics of a pentacene molecule and red crosses representing oxygen molecules. Underneath are AFM images that show blobby/blurry outlines of these molecules

Source: © Science/AAAS

Individual pentacene’s triplet lifetime – and how it is cut short by a nearby oxygen – measured with atomic resolution

Researchers have observed electrons jumping between different energy levels in an individual molecule, and how the jumps can be suppressed when the excess energy is transferred instead to a nearby oxygen molecule – a process called quenching.

By positioning the two molecules on a surface with atomic precision, the team could study how quenching is affected by their geometric arrangement. Such energy transfer between molecules is a fundamental process in chemistry and life, for example in photosynthesis.