All Reactions and synthesis articles
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SponsoredDNA-compatible C–H activation method set to benefit drug discovery
Larger and more diverse DNA-encoded libraries on the cards thanks to new tool
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Research
Retro-Diels–Alder study links solvent viscosity to reaction rate under microwave heating
New study helps to establish the parameters for microwave-specific rate enhancements observed in certain reactions
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Research
Hybrid light–matter particles offer tantalising new way to control chemistry
Early experiments are revealing that vacuum-field catalysis could make reactions happen with mirrors and nothingness
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Research
Nano-stirrer bars for microscale mixing made via continuous electrospinning method
Tiny stirrer bars could simplify the design of microfluidic platforms
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Research
Ultra-fluorinated cyclohexane shows off two faces
1,2,3,4,5,6‐hexakis(trifluoromethyl)‐cyclohexane is the most sterically crowded all-cis derivative
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Research
IBM seeks to simplify robotic chemistry
RoboRXN system extends AI approach to extracting and checking chemistry information from patent literature to programming automation
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Research
Open-air performance for atom transfer radical polymerisation
Sodium pyruvate plays a lead role by regenerating the catalyst and scavenging hydrogen peroxide
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Research
Sound choreographs chaotic reactions
Bass tones create reproducible patterns in unpredictable out-of-equilibrium systems
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Feature
Ammonia synthesis goes electric
James Mitchell Crow finds that the outlook for renewables-powered electrochemical ammonia production is beginning to brighten
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Research
Superfluid helium nanoreactor takes single atom catalysis understanding to the next level
Gold alters bond energies to catalyse dissociation reaction
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Research
Aniline synthesis turns to photochemistry to access challenging targets
New photochemical strategy could jump in where common cross-coupling reactions fall short
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Research
Hydrogen bond imparts more stability on transition state than expected
Study reveals importance of repulsive interactions
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Research
Smart stirrer bar monitors while it mixes
$20 stirrer can send real-time reaction data to your smartphone
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Research
Triple mechanochemistry mechanism might be a first for organic chemistry
Discovery of how molecular tuning influences mechanism could be used in self-healing polymers or in plastics that break down upon mechanical activation
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Research
NMR findings suggest solution to enhanced diffusion dispute
Energy release rate may solve the puzzle of why the phenomenon is seen in some systems but not others
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Opinion
Rewriting the narratives surrounding radical transformations
Don’t let tired clichés get in the way of selective and sustainable chemistry
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Research
AI reactivity predictor considers both molecular and electronic properties
Machine-learning model tested on electrochemical systems
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Research
Surface sites on gold catalyst edited to control regioselectivity of a click reaction
Steric hindrance created by phosphine ligands restricts how substrates approach catalyst
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Research
Introducing the tubulararenes, a new class of strained aromatic compounds
Electroactive container molecules built from the bottom-up
