Atoms and bonds – Page 5
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Research
First synthesis of unusual arsenic reagent reveals that it breaks periodic trend
Electron deficient arsenic intermediate challenges preconceptions of heavy main group elements
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Research
Formation of chiral centres monitored in real time
Michael addition observed at single-molecule level
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Charge-transfer interactions during C–H activation directly observed
New insights could guide the design of better catalysts
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Identifying single atoms with x-ray specificity
Combining synchrotron x-rays with scanning tunnelling microscopy gives atomic resolution
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Metallic hydrogen and diamonds may have been made from plastics
A combination of x-ray diffraction experiments and simulations suggests that an intense laser can transform polystyrene
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Optical microscopy with Ångström resolution could revolutionise how we see life
Technique can distinguish between details that are just a few atoms apart
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Increase in aromaticity drives metallaaromatic ring contraction
Acid-promoted ring contraction reaction reshapes an osmaindenol into an osmapentalene
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Molecular twist enhances stability of biphenyls
Study suggests that decaphenylbiphenyl is not a high-energy molecule, despite being crowded and seemingly strained
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New neural networks calculate catalysts’ adsorption energy ‘with lightning-fast speed’
AI has been used to overcome the problems of modelling massive molecules on metal surfaces, which could accelerate the design of efficient catalysts
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Research
Study untangles friction and surface chemistry in chemically damaged hair
Researchers develop system that can be used to screen the tribological performance of hair care formulations
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Research
Nanoparticles poison single-atom cross coupling catalyst
In a classic heterogeneous palladium catalyst, less than 1% of metal does 99% of catalytic work
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Research
Melodies make molecules manipulable with musical machine models
Software represents molecules with sounds, rather than text and pictures
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Research
Extraordinary crystal structure displays abiotic foldamer with unprecedented complexity
Four aromatic oligoamide helix-turn-helix units assemble in organic solvent into an abiotic architecture with quaternary-like structure
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Skeletal editing provides a simple route to access isoquinolines
Direct nitrogen atom insertion into a broad range of indenes and cyclopentadienes
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‘Dynamic bonds’ reshape the rules of aromaticity and chirality
Discoveries could contribute to new understanding of organic chemistry, triggering applications in catalysis and materials science
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Research
Harvesting water from the air with organic crystals
Discovery could lead to novel technologies for fighting water scarcity
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Research
Machine learning ecosystem evolves MOF design
Mofdscribe handles all stages from collecting data to evaluating performance
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Research
New example of molecular chirality discovered
The first instance of a molecule in which an oxygen atom is the sole stereocentre has been reported
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Research
AI identifies molecules from their featureless visible spectrum
Forget about trying to interpret peaks and let machine learning identify organic compounds from their entirely smooth visible spectrum
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Research
Chemists put the colour-changing ‘ouzo effect’ under the microscope
Greater understanding of the anise-flavoured spirit’s cloudy mix could lead to better emulsions