Collective bonding continues to divide opinion

Figure

Source: © Cina Foroutan-Nejad/Polish Academy of Sciences

New research supports counterintuitive explanation, but debate is far from settled

When chemists first synthesised NaBH3 back in 2019, initial research suggested a dative bond connected its sodium monoanion with a borane Lewis acid. Theoretical chemists, however, quickly established that the bonding was not that simple.