All Molecular chemistry articles
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ResearchControversy surrounds corrected chemical structures
Researchers used machine learning-powered NMR prediction to correct improbable structures – but some of their revisions have been challenged
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Feature
When will molecular electronics make the connection?
Computer chips based on single molecules may remain a work in progress, finds James Mitchell Crow but the technologies developed along the way are being used by chemists to explore their reactions
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Research
Perfluorocubane catches electron in molecular box
Cube-shaped molecule can hold a single electron – a real-life version of the ‘particle in a box’ principle from quantum mechanics textbooks
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Opinion
Beyond the transition state
Entropy production could be a key guide to predicting how a reaction product forms
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Research
First fundamentally new form of adsorption for more than 90 years driven by molecular machines
Unlike physisorption and chemisorption, the newly discovered ‘mechanisorption’ is an active process that can store energy or chemicals
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Research
Method to make unusual oligonucleotides could be a boon for gene therapy drugs
Synthesis can insert unusual linkages into DNA molecules while rivalling industry standard chemistry in speed and efficiency
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Research
Giant molecular cage protects plastic-eating enzyme
Caged protein withstands temperatures much hotter than its usual melting point and becomes 1000 times more resistant to solvents
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Research
No more worrying about nomenclature – AI will tell you what that chemical is called
Open-source online resource converts organic chemical structures to their Iupac names and vice versa
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Opinion
Are we giving chemicals bad names?
Does it matter that we use a mixture of old and systematic names for chemicals?
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Research
Three-centre single-electron bond caught in a cage
Fullerene cage stabilises bond never before seen in lanthanide chemistry
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Opinion
Space, energy and synthetic half-reactions
Matching driving forces with intermediates to predict new chemistry
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Opinion
When does a hydrogen bond become a covalent bond?
Ultrafast infrared spectroscopy probes the character of the short, strong bonds in HF2–
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Research
Knotted molecules can transfer chirality from the nano to the macroscale
Simply unknotting a molecule added to liquid crystals can invert their chirality
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Opinion
Molecular dynamics used to simulate 100 million atoms
At the point of simulating bulk matter
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Research
First glimpse caught of how a molecule changes when it absorbs light
X-rays enable direct observation of the initial step of a light-driven reaction
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Research
Molecular cages give amides a twist to increase reactivity up to 14 times
Squeezing amides into twisted conformation inside nanosized cages makes them easier to hydrolyse
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Research
Largest molecular wheel ever made pushes limits of aromaticity rules
Giant, 162 π-electron aromatic ring shows that we haven’t reached the upper limit of Hückel’s rule yet
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RSC
The future of chemistry: Science Horizons and Chemistry Means Business
Hundreds of scientists contributed to the Royal Society of Chemistry’s Science Horizons report to build a picture of the challenges and opportunities the next generation will bring
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Opinion
The silent rise of the robots
Mechanical helpers have been creeping into our labs for decades
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Research
Floppiness scale untangles knotted molecules
Chemists use floppiness factor to characterise mechanically interlocked molecules using mass spectrometry
