All-metal ion mimics carbonate

Metal carbonate analogue

Source: © Wiley-WCH

Seven month reaction delivers peculiar tin–bismuth anion that is first solution-stable all-metal carbonate analogue 

 It’s shaped like carbonate, has the same 24 valence electrons and resonance structures, but is made completely out of metal atoms. This is the tin-bismuth anion [SnBi3]5, the first all-metal carbonate analogue known to exist in solution.