Organometallic compound found to break textbook principle

Structure

Source: © Satoshi Takebayashi et al 2025

A ferrocene-derived complex is a further exception to the 18-electron rule

A new derivative of ferrocene has 20 valence electrons, challenging the longstanding rule that organometallic compounds can only have a maximum of 18. The researchers highlight that the ligand structure alters the redox properties of the complex, offering improvements for current catalysts and materials.