Organometallics – Page 2
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ResearchFirst x-ray structure of radium compound gives glimpse of element’s coordination chemistry
Oak Ridge National Laboratory team determines the single crystal structure of a radium complex
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ResearchIncrease in aromaticity drives metallaaromatic ring contraction
Acid-promoted ring contraction reaction reshapes an osmaindenol into an osmapentalene
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OpinionN-heterocyclic carbenes are more than passive spectators
The practical importance of N-heterocyclic carbenes continues to grow
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ResearchTime-resolved spectroscopy shines new light on migratory insertion mechanism
Using lasers to probe metal-centred reactions leads to new understanding of highly reactive catalytic intermediates
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CareersThe nickel crystal that catalysed collaboration
An apparent scooping turned into something much more valuable
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ResearchStrange new bonds found hiding in plain sight in common organometallics
Collective interactions are proof that there’s more to bonds than just connecting neighbouring atoms
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ResearchMetal switches on iodine’s σ-hole
Iodine’s halogen-bonding ability can be switched on and off by creating ruthenium sandwich
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ResearchMashed magnesium used to prepare Grignards without worrying about air
Mechanochemical method avoids inert gas and dry solvents in classic organometallic reaction
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![An image showing a [M2(BzN6-Mes)]n− complex](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/4/0/8/514408_index_128835.jpg)
ResearchMetal sandwich stabilises first benzene triplet-state aromatic
Benzene diradical dianion is the first monocyclic molecule that’s Baird aromatic in the ground state
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FeatureSupermetals versus superbugs
With pathogenic bacteria rapidly overcoming our arsenal of organic antibiotics, James Mitchell Crow asks if it is time to revisit metal-based antimicrobials
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ResearchMacrocyclic NHC ligands serve up trio of new actinide sandwich complexes
Delocalised, anionic macrocyclic NHCs with unusually strongly σ-donation set to expand suite of stable organometallic complexes with f block cations
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ResearchCalculations predict first quadruple bond between a transition metal and silicon
Silicon–ruthenium interaction adds to flurry of research on multiple bonds
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NewsTributes paid as Royal Society of Chemistry past president Eddie Abel dies
Organometallic chemistry giant passes away aged 89
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ResearchOrganometallic manganese cluster resembles nesting dolls
Researchers make an intricate structure with a strong magnetocaloric effect
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ResearchIridium pincer complex promotes unprecedented ether decarbonylation
Scientists stumble upon unique transformation that involves breaking an extraordinary number of bonds
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OpinionThe Nobel prize that got binned
Ferrocene is a classic example of a discovery that was dismissed as a failed experiment
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ResearchA whole new world for barium, including first ever non-ionic barium fluoride
Ligand tames barium, making precursor to first barium–tin and first molecular barium–fluorine bond
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ResearchMetal complexes outperform organics in antimicrobial analysis on crowdsourced compounds
Could this study prompt drug developers to rethink their reluctance to making metal-based pharmaceuticals?
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ResearchInorganic fragment library ready to help drug discoverers reach neglected regions of chemical space
A new approach to fragment-based drug design
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NewsDoes the periodic table make more sense upside down?
UK researchers argue an inverted table works better for students
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