Organometallics – Page 3
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ResearchIridium pincer complex promotes unprecedented ether decarbonylation
Scientists stumble upon unique transformation that involves breaking an extraordinary number of bonds
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OpinionThe Nobel prize that got binned
Ferrocene is a classic example of a discovery that was dismissed as a failed experiment
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ResearchA whole new world for barium, including first ever non-ionic barium fluoride
Ligand tames barium, making precursor to first barium–tin and first molecular barium–fluorine bond
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ResearchMetal complexes outperform organics in antimicrobial analysis on crowdsourced compounds
Could this study prompt drug developers to rethink their reluctance to making metal-based pharmaceuticals?
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ResearchInorganic fragment library ready to help drug discoverers reach neglected regions of chemical space
A new approach to fragment-based drug design
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NewsDoes the periodic table make more sense upside down?
UK researchers argue an inverted table works better for students
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ResearchDesigner copper complexes offer route to cheaper organic LEDs
New material cuts out precious metals
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ResearchMolecular shapeshifting observed at ultrafast speeds
Study reveals that structural transformations occur just as fast as molecular vibrations
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ResearchAlkaline earth carbonyls break the rules
Complexes of Ca, Sr and Ba adopt a transition metal-like 18-electron configuration, rather than the octet more usually found in main group compounds
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ResearchCopper–arene complex tamed by silylene
Ligand selection unleashes first monomeric [Cu(η6-C6H6)]+ complex
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ResearchTitanium complex converts methane to alkenes at room temperature
New work illustrates the ‘crucial steps’ required for a process to make useful chemical feedstocks from methane
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Podcasttert-Butyl lithium or t-BuLi
A pyrophoric reagent that remains one of chemistry’s staples and the liquid salts that can tame its wild reactivity
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OpinionNickel catalyst couples alcohols and carbon dioxide
Flexibility and low cost make nickel a firm favourite in catalysis
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ResearchBringing ferrocene full circle
Cyclic oligomers made from iconic organometallic compound hold possibilities for electronics
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ResearchRare mixed-valent Si2H radical isolated
N-heterocyclic carbenes used to trap subvalent disilicon hydride species
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PodcastTetraethyl lead
For decades, automobile fuel had a dangerous additive: Tetraethyl lead. Matt Gunther explains why a toxic compound was added to our fuel
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ResearchQuintuple bond activates small stable molecules
Exotic complexes suggest route to synthetic feedstock
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FeaturePaving the way to polythene
It is 50 years since Karl Ziegler and Giulio Natta won the Nobel prize for their work on polymers
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