Atoms and bonds – Page 11
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Research
XFELs make small molecule crystallography without crystals possible
High-speed technique allows structures of difficult molecules to be determined
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Dilanthanide complexes smash record for strongest single-molecule magnet
Complexes featuring first ever lanthanide–lanthanide bond could offer way to make powerful new permanent magnets
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Shortest-lived and lightest magnesium isotope ever too unstable to even attract electrons
Magnesium-18 cation has a fleeting half-life of 3 billion trillionths of a second
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Listening to quantum beats could reveal rhythm of birds’ migratory compass
Laser technique to read out oscillating spin states could help uncover how animals’ magnetic sense works
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Case closed on how surfactant micelles create mesopores within zeolites
Raman spectroscopy unveils key step in the formation of heterogeneous catalysts
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Berkelium complex opens door for future nuclear recycling
Complex is only the sixth ever created
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Algorithm out of Google’s DeepMind finesses DFT calculations
Machine learning creates algorithm that avoids large errors in solutions to certain problems
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Mashed magnesium used to prepare Grignards without worrying about air
Mechanochemical method avoids inert gas and dry solvents in classic organometallic reaction
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Rare red californium sandwich pushes frontier of isolable molecules
Researchers rehearsed metallocene’s synthesis with other elements before using just two milligrams of the precious radioactive actinide
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Diels-Alder reaction directly observed under the microscope
Simple ring-forming reaction followed on a surface for the first time using scanning probe microscopy
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The diamond family welcomes its newest member – paracrystalline diamond
Amorphous diamond with pockets of natural diamond makes theoretical paracrystals a reality
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Unsupervised machine-learning tool could accelerate catalyst discovery
The approach was able to identify phosphine ligands that may form dinuclear palladium(I) complexes using only five experimental data points
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First inspection of σ-hole reveals its peculiar shape
Atomic force microscopy snaps first experimental images of halogen bond’s charge distribution
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Electrostatic origins of specific ion effects revealed
Ion–solvent Coulomb interactions explain ordering of Hofmeister series, new study claims
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Doubly negative dianions can form π hole bonds too
Researchers report an attractive interaction between two doubly negative dianions for the first time
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Quantum double-slit experiment done with molecules for the first time
Researchers prepare ‘new type of matter’ to conduct classic wave–particle duality experiment
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Minority Report-esque AI predicts new designer drugs before they’re made
Machine learning program accurately predicts structure of unknown psychoactive substances from mass spectra alone
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First firm evidence for ferroelectric ice
Water becomes electrically polarised when sandwiched between graphene sheets
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Molecular Newton’s cradle challenges theory of transition states
Nanoscale trick-shot sees fluorine atoms knocked along chain
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Textbook electronegativity model fails when it comes to carbon–halogen bond strengths
Computational analysis finds that it’s size, not electronegativity differences, determining bond strength within periodic table groups