Copper–arene complex tamed by silylene

The molecular structure reveals the h6 coordination mode of benzene to the Cu center

Source: © Royal Society of Chemistry

Ligand selection unleashes first monomeric [Cu(η6-C6H6)]+ complex

Inorganic chemists working in Spain and India have isolated the first unsupported example of a monomeric copper cation where the copper atom bonds to a benzene ring in the η6 bonding mode.