Copper brings glow to triple-bonded boron

Phosphorescent complex

Source: (c) Dr Theresa Dellermann

Unexpected reaction between boron–boron triple bond and transition metals revealed

The side-on connection of a boron–boron triple bond to a metal has expanded the repertoire of metal-bound triple bonds beyond purely organic alkyne ligands. This has enabled chemists to form π complexes with copper(I) atoms, one of which has an intense phosphorescence in the red to near-infrared region of the electromagnetic spectrum.