Largest molecular wheel ever made pushes limits of aromaticity rules

An image showing the cover art

Source: © Michel Rickhaus/University of Zurich

Giant, 162 π-electron aromatic ring shows that we haven’t reached the upper limit of Hückel’s rule yet

Hückel’s rule, developed to explain the properties of the six aromatic electrons in benzene, is still valid for a giant aromatic ring with 162 π electrons that is many times the size of the simplest aromatic.