Mechanochemistry first as reaction driven by pressure

This illustration shows complexes of soft molecules (yellow and pink) attached to “molecular anvils” (red and blue) that are about to be squeezed between two diamonds in a diamond anvil cell. The molecular anvils distribute this pressure unevenly, breakin

Source: © Peter Allen / UC-Santa Barbara

A redox reaction triggered by squeezing a crystal results in the ejection of copper nanoparticles

Squeezing a cleverly designed crystal can trigger the creation of nanoparticles in the first example of a pressure-driven mechanochemical synthesis.1 Computer models of the crystal’s structural change under pressure provide atomic-level insight into how force transforms into chemical reactivity, a process that is still a mystery for many mechanochemical reactions despite being known about centuries.