Triple mechanochemistry mechanism might be a first for organic chemistry

An image showing the mechanism

Source: © Guillaume De Bo

Discovery of how molecular tuning influences mechanism could be used in self-healing polymers or in plastics that break down upon mechanical activation

Researchers discovered an force-induced carbon–carbon bond rupture that follows three different mechanistic pathways at the same time – a first for mechanochemistry and possibly for organic chemistry, according to the study’s leader Guillaume De Bo from the University of Manchester, UK. Tuning the bond’s polarity influences which mechanism becomes dominant, which could help chemists make self-healing materials or plastics that break down under mechanical strain.