Rotaxane–gold complex is in good shape for catalysis
A new type of catalyst containing a mechanically planar chiral rotaxane shows promise for organic synthesis
Mechanical chirality could soon find a place in catalysis, offering new ways to make important molecules, UK scientists say. The team has created a gold complex incorporating a mechanically planar chiral rotaxane and used it to mediate an organic reaction, demonstrating the potential of using mechanical bonds for selective synthesis.