All quantum tunnelling articles
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ResearchQuantum tunnelling drives aromaticity flip-flop
Augmented pentalene structure could be a molecular Schrödinger’s cat, aromatic and antiaromatic at the same time
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NewsMacroscopic quantum mechanical tunnelling wins Nobel prize in physics
John Clarke, Michel Devoret and John Martinis honoured for their observations of quantum effects in a superconducting electric circuit
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ResearchFluorine surprises by becoming heaviest atom ever to quantum tunnel
First experimental evidence of tunnelling in fluorine pushes the boundary of our understanding of chemical bonding
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ResearchQuantum tunnelling explains why several supposedly stable benzene isomers will never be made
Research highlights importance of considering quantum effects in computational studies on strained molecules
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ResearchChloride ions tunnel free from PVC
Computational clues uncover quantum escape route from common plastic
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ResearchInstanton theory extended to describe quantum tunnelling through a conical intersection
Quantum pathfinding cuts computational burden and offers fresh insights
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ResearchIdentifying single atoms with x-ray specificity
Combining synchrotron x-rays with scanning tunnelling microscopy gives atomic resolution
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ResearchUnprecedented simultaneous quantum tunnelling reaction discovered
Isomers of the same molecule undergo different tunnelling rearrangement at the same time – a process that ‘is completely breaking the classic transition state rules’
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ResearchQuantum tunnelling enhances ozone decay
The OH + HCl → H2O + Cl reaction rate is boosted by strong hydrogen bonding, which generates quantum transition states
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ResearchHeavy-atom quantum tunnelling catalysed with Lewis acids
Lewis acid–base interactions found to increase quantum tunnelling rates of rearrangement reaction
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ResearchElectric fields flick the quantum-tunnelling switch in cold reactions
Reaction kinetics affected by direction of external electric field under cryogenic conditions
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OpinionWhen does a hydrogen bond become a covalent bond?
Ultrafast infrared spectroscopy probes the character of the short, strong bonds in HF2–
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ResearchHow tunnelling titanium turns a perfect crystal into a bad heat conductor
Quantum tunnelling is key to solving the mystery of why some defect-free crystals have such low thermal conductivities
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NewsExplainer: What is quantum tunnelling?
Welcome to a weird world where reactions that ought to be impossible occur regularly
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ResearchRubidium atoms’ tunnelling time measured with quantum stopwatch
Ultracold atom’s time inside forbidden barrier determined, but experiment might not resolve the controversy surrounding tunnelling time
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ResearchQuantum dot heat engine works without moving parts
Similar systems could be used to generate electricity from waste heat in solar cells
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ReviewBeyond weird: why everything you thought you knew about quantum physics is different
Philip Ball sets himself the task of explaining quantum mechanics
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ResearchStudy confirms long-distance quantum tunnelling in thiourea
Validation for unusual proton-transfer process first observed 15 years ago
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ResearchCall for chemists to stop ignoring quantum tunnelling
Deeper insights into reactions and how to build artificial enzymes could await those who come to terms with quantum phenomenon
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ResearchHuge molecular fragment quantum tunnels in everyday lab reaction
First example of a whole trifluoromethyl group sneaking through an energy barrier