All Reactions and synthesis articles – Page 47
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ResearchHypervalent iodine reagent’s aversion to conversion
A case of mistaken identity inspires a closer look at the structural stability of Togni reagent I
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ResearchNew type of hydrogen bond discovered
First non-classical hydrogen bond involving boron–hydrogen to π-system observed
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ResearchChemists get the ball rolling on titanium oxide fullerenes
Titanium oxide nanocluster has been captured under electron microscope
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ResearchMolecular surgery stitches up water dimer in fullerene cage
First isolation of dimer to aid fundamental studies of hydrogen bonding
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ResearchElectrostatic field powers up reaction rate
Applying electrical potential to Diels-Alder system confirms prediction of catalytic effect that defies received chemical wisdom
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ResearchNanosynthesis under flow is far less slow
‘Dial-a-particle’ strategy tunes the size and shape of nanostructures
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ResearchCatalyst offers cheaper route to disinfect water
Nanoparticles can be used to produce small amounts of hydrogen peroxide with less precious metals in straightforward process
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ResearchChemists hit a top synthetic target with pyramidal compounds
Non-classical covalent pyramidanes surprise with high bonding ionicity
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ResearchBoat conformer launches new carbon bond-forming reaction
Palladium catalyst exploits usually hard-to-access configuration to achieve C–H activation
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ResearchNew process draws poison from nitrile production
Nickel and aluminium catalysts obviate need for explosive and toxic hydrogen cyanide used to make important precursors for pharmaceuticals, cosmetics and agrochemicals
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ResearchIncredibly rare and unstable mineral shows catalytic clout
Georgeite shows promise as a catalyst precursor for the synthesis of methanol
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OpinionDead in the water
A healthy sense of hydrophobia is a useful trait in the plant, says Chemjobber
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Research‘Forbidden chemistry’ drives carbon bond forming sequence
Flow process harnesses unstable diazo compounds in room temperature reactions
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ResearchA small molecule’s big moment
Substituted benzene has the largest dipole ever observed in a neutral molecule
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ResearchDrug labelling problems ironed out by new catalyst
Cost-effective method to tritiate compounds offers way to track drug metabolism while minimising radioactive waste
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ResearchEasy addition of ‘unnatural’ strained rings boon for drug chemists
Technique can slow metabolism of medicines, giving them more time to work
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ResearchFirst nitrido–imido–amido complex made
Intriguing compound has single, double and triple Cr–N bonds from the same chromium atom