All Matter articles – Page 36
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Research
Vibrational energy antenna offers ‘a completely new way to run a reaction’
First infrared analogue to natural light-harvesting systems drives isomerisation
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New web apps help standardise how chemists assign colours to MOFs
Survey highlighting the subjective nature of colour prompts scientists to create new tools to improve chemical records
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Feature
How rubber is bouncing back
From their colonial roots to future alternatives, Kit Chapman looks at the chemistry of natural elastomers
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Ultrasound tops traditional synthesis in hunt for elusive golden polymer
Mechanochemical synthesis of fluorinated polyacetylene shows that mechanical force can tackle transformations that are near impossible with solvent-based chemistry
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Hybrid resin offers new dimension in flow reactor printing
New resin enables chemical resistance, UV transparency and the potential for surface functionalisation
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First flat tetravalent silicon stabilised by metals and aromaticity
Chemists make stable compound featuring a silicon atom that forgoes tetrahedral geometry
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Beryllole is the first alkaline earth metal antiaromatic molecule
Metallacyclopentadiene is the first beryllium compound to engage in π system chemistry
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DFT boosts machine-learning models of nucleophilic aromatic substitution reactions
Best of both worlds for computational organic chemistry predictions
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How tunnelling titanium turns a perfect crystal into a bad heat conductor
Quantum tunnelling is key to solving the mystery of why some defect-free crystals have such low thermal conductivities
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Heavy-metal cluster sets size record for metal aromaticity
12 bismuth ring creates ‘substantial’ π aromaticity with only two aromatic electrons
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Mechanochemistry makes ammonia under mild conditions
Ball-milling process could reduce energy consumption associated with key fertiliser feedstock
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Explosive imaging captures helium dimer’s wave function
Technique could provide insight into other exotic states
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258-atom endless knot created with thiazole ligands
Closed loop structure resembles Celtic and Buddhist symbols
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Microscopy technique enables detailed imaging of nucleation process
Phase-enhanced environmental SEM allows researchers to probe droplet and bubble formation
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Fluorescent molecule breaks size record for green-emitting dyes
Study identifies 14-atom fluorophore with range of potential biological applications
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Pasta-shaped structures explain chiral light emission in polymers
Enhanced molecular model could lead to thinner and more efficient OLED displays
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Solar cells perovskite films made at record low cost and speed
‘First industrially relevant attempt’ to scale up perovskite solar cell manufacturing makes 12 meters of material per minute, with one meter costing only $0.25
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Feature
Sustainable Covid-19 protection
Discarding our pandemic face masks could be an environmental disaster. Clare Sansom looks at the alternatives
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Intricate supramolecular rosette demonstrates power of cooperative interactions
Rosette assembles inside porphyrin nanoring when all components are present
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Conduit coated with bioink encourages damaged nerves to reconnect
New electro-conductive system is fully biodegradable