Organic chemistry – Page 25
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ResearchTaking the pressure off catalytic carbon dioxide conversion
Chemists obtain formate from carbon dioxide at atmospheric pressure without using hydrogen gas
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ResearchWalking radicals relocate double bonds
Nickel-guided radicals walk along carbon chains to make E-alkenes from terminal alkenes
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ResearchForceful treatment stabilises drug antibody linkages
Ultrasonic energy could modify maleimide–thiol connections in cancer treatments in volume
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OpinionIn search of ultimate selectivity
A catalyst that reacts only with aryl iodides, spurning bromides and chlorides
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ResearchFlexible route to enantiomerically enriched cyclobutanes
System for modifying square starting molecule could be gateway to numerous bioactive molecules
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![A picture showing the molecular structure in the solid state of [(C2F5)(F3C)2CO]2](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/8/6/2/140862_Index-image-superfluorinated.jpg)
ResearchSuperfluorinated peroxides surprise with stability
Fluorinated peroxides more stable than their non-fluorinated counterparts
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ResearchDroplets retain crystal-like structure while sliding on vertical substrate
Surprising properties of soft material may have significant impact on polymer physics
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ResearchScreening strategy pursues photocatalytic couplings for drug discovery
High-throughput screening and flow-based scale-up combo identifies chemistry needed to functionalise drug fragments and obtain useful amounts of product
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ResearchPatent-busting AI tool navigates around protected drug pathways
Organic retrosynthesis software can identify key bonds involved in patented reactions to find alternative pathways
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ResearchCrowdsourced drug discovery pits half-forgotten compounds against neglected diseases
45 research groups donate 350 compounds to the first crowdsourced screening library
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ResearchBenzene transformed into nanotubes with predictable defects
Synthesis delivers molecular cylinders that contain 240 sp2-carbon atoms
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PodcastEllagic acid
Louise Crane introduces the antioxidant that led to exaggerated claims that 'whisky helps fight cancer'
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ResearchEnzyme evolved that can perform reactions new to nature
New possibilities for organic synthesis with enzymatic C–H functionalisation
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ResearchBlood pressure drug reacts with membrane lipids
Lipidation products add to evidence that biological membranes are far from chemically inert
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ResearchNew tools direct reactions at specific C–H bonds in organic molecules
Elegant catalysts offer quicker routes to complex compounds
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BusinessHow many papers do you read a week?
Everyone needs a strategy to keep up with the literature
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ResearchLight catalyst breaks mirror symmetry in first reverse racemisation
Transformation makes single mirror image molecules in a ‘completely different way of doing enantioselective chemistry’
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ResearchDwarf planet Ceres turns out to be extra-carbony
Asteroid belt’s largest object, thought to be a piece of rock, contains up to 20% carbon
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ResearchWeird mechanism behind catnip compound’s biosynthesis uncovered
Nepetalactone – the compound cats go crazy for – is made by a two-step procedure that is unlike any other in terpenoid biosynthesis