Inorganic chemistry – Page 6
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ResearchElectrochemical wizardry conjures nitrate at room temperature from air
Process could cut the huge carbon footprint of fertiliser production
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ResearchRedox reactions ‘mine’ old fluorescent light bulbs for europium
In just three simple steps rare earth element can be recovered, avoiding ‘ecologically devastating’ mining
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ResearchDimetallocene with two different metal centres synthesised for the first time
Molecule first theorised 20 years ago created in the lab
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ResearchNew metal-free MOFs show early promise for nuclear chemistry
Discovery of counterparts to metal-organic frameworks guided by crystal-structure prediction tools
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ResearchPromethium bond length completes picture of the size of lanthanides’ atoms
Study fills one of the last gaps in our knowledge of the periodic table
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OpinionThe 1920s chemists who thought they’d achieved the alchemists’ dream
The now-forgotten transmutation controversy hung on apparent evidence of mercury transforming into gold
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ResearchSingle atom layer of gold produced for the first time
Goldene synthesised via etching technique used in Japanese knife-making
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ResearchIodide addition could make high energy lithium-sulfur batteries commercially viable
Next generation batteries given self-healing properties and vastly improved electronic conductivity by sulfur iodide inclusion
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ResearchDebate surrounding amorphous selenium’s structure rumbles on
New evidence suggests that amorphous selenium forms eight-membered rings, but some researchers believe the results are inconclusive
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ResearchBoron cluster family breaks electron counting rules
Rare structures have unusual deltahedral shapes
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OpinionHigh entropy or just complex?
Several elements mixed in a single crystal phase isn’t necessarily a high entropy material
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FeatureMarvellous mixtures of metals
High entropy alloys, with anywhere from five or more different metals, have unusual properties and could find use in a variety of high-tech applications. Clare Sansom reports
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ResearchPlutonium to carbon double bond a first
Findings offer insight into differences in chemical reactivity between actinides and lathanides
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ResearchUnusual bridging fluorine discovered in one-of-a-kind interhalogen ion
Similarity to MgAgAs crystal structure takes researchers by surprise
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OpinionA milestone year
2024 is set to be a special year for Chemistry World because it’s 20 years since we published our first issue
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NewsThe story of how the most successful US–Russia scientific collaboration collapsed
Five jointly discovered superheavy elements completed the eighth row of the periodic but then Russian revanchism reared its head
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ResearchRobotic chemistry lab joins forces with Google AI to predict then make new inorganic materials
Algorithm discovered more than 2 million inorganic structures
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FeatureWhen a bond gets too extreme
Chemical bonds are part of the way chemists rationalise the behaviour of atoms in the conditions of the world around them. Tim Wogan looks at how they are affected when those conditions change
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FeatureReaching into the non-covalent toolbox
Alongside supramolecular stalwarts, budding bonding forms are vying to be valuable, finds Andy Extance
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ResearchScientists may have detected exotic nitrogen-9 isotope
Nuclei would be the first to decay by the emission of five protons