Inorganic chemistry – Page 8
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ResearchHammett equation parameters optimised for improved predictive power
Update overcomes limitations and eliminates human biases intrinsic to the original formulation
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ResearchIridium pincer complex promotes unprecedented ether decarbonylation
Scientists stumble upon unique transformation that involves breaking an extraordinary number of bonds
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OpinionThe Nobel prize that got binned
Ferrocene is a classic example of a discovery that was dismissed as a failed experiment
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ResearchSolar cell concept used to enhance nuclear battery
New device uses a ruthenium dye to absorb beta radiation
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ResearchBaird’s rule of aromaticity extended to all-metal systems
Aromaticity concept can help scientists understand the properties of metal clusters
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ResearchSalt crystal grows legs to avoid slippery surface
Sodium chloride’s self-lifting crystallisation has been observed for the first time
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OpinionStefanie Horovitz – the woman behind the isotope
Overlooked by history, murdered by the Nazis: the forgotten story of a talented chemist who helped prove the existence of isotopes
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ResearchLargest hollow cage molecule yet made from 1000 atoms
Giant polyoxymetalate cluster contains 240 molybdenum, 740 oxygen and 20 sulfur atoms
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OpinionMarguerite Perey and the last element in nature
Kit Chapman tells the story of the chemist who discovered francium, but was almost denied the credit
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PodcastHexasilabenzene
Brian Clegg discovers what a six-membered silicon ring can tell us about alien life
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ResearchNew bond discovered among spodium elements zinc, cadmium and mercury
Group 12 joins the σ-hole interaction family with spodium bonds
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FeatureMetalloenzyme mastery
There are natural metalloenzymes that make difficult chemistry look easy. James Mitchell Crow talks to the bioinorganic chemists figuring out how to copy them
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ResearchStrange hexagonal form of table salt discovered
Predicted by an evolutionary algorithm, the first hexagonal sodium chloride was made on a diamond surface
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ResearchNew high pressure allotrope of nitrogen solves a chemical mystery
‘Black nitrogen’ shares similarities with other elements in its group on the periodic table – answering the question of why nitrogen normally doesn’t
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ResearchMolecular experiments hope to reveal new physics
Detecting extremely short-lived radium fluoride can explore standard model’s limits
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ResearchNew silicon–silicon bond is a rare example of a π bond without a σ bond
Discovery made in silicon analogue of bicyclobutane
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ResearchShock treatment makes nanocatalysts from metals that are ‘impossible’ to mix
New technique allows nanoparticles to be produced from almost any combination of metals
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ResearchPushing praseodymium past its oxidation limits
Researchers isolate the first molecular species bearing praseodymium(IV), which could find applications in catalysis and new materials