Inorganic chemistry – Page 9
-
ResearchOrganometallic manganese cluster resembles nesting dolls
Researchers make an intricate structure with a strong magnetocaloric effect
-
ResearchDouble bond metathesis extended to germanium compounds
Partner swapping reaction carried out with digermene compounds, with no need for a catalyst
-
ResearchCations pairs exhibit surprising attraction
‘Complex of complexes’ containing silver and iodonium ions experience an unprecendented interaction
-
ResearchHalf the world’s supply of element 99 used to reveal its chemical secrets
Scientists explore einsteinium’s unusual chemistry using less than 200 nanograms of the precious and highly radioactive material
-
ResearchHoles cause sodium nitride to behave like a metal
Clathrate’s strange metallic nature caused by electronically active cavities
-
ResearchFirst flat tetravalent silicon stabilised by metals and aromaticity
Chemists make stable compound featuring a silicon atom that forgoes tetrahedral geometry
-
ResearchBeryllole is the first alkaline earth metal antiaromatic molecule
Metallacyclopentadiene is the first beryllium compound to engage in π system chemistry
-
ResearchHeavy-metal cluster sets size record for metal aromaticity
12 bismuth ring creates ‘substantial’ π aromaticity with only two aromatic electrons
-
Research258-atom endless knot created with thiazole ligands
Closed loop structure resembles Celtic and Buddhist symbols
-
PodcastIonic liquids
Liquid salts, ionic melts, fused salts, or ionic glasses – call them what you like, these much-hyped solvents show great promise
-
ResearchNew ordering of elements could help find materials with promising properties
Universal sequence of elements index uses atomic radii and electronegativity to make predictions about simple compounds
-
ResearchTrinuclear complex is a rare example of bottled double aromaticity
First report of a system containing a ruthenium atom that takes part in two different types of aromaticity simultaneously
-
ResearchPlanar fivefold bonding with silicon and germanium at the centre
Electronegative elements key to stabilising exotic structures, simulations show
-
ResearchHammett equation parameters optimised for improved predictive power
Update overcomes limitations and eliminates human biases intrinsic to the original formulation
-
ResearchIridium pincer complex promotes unprecedented ether decarbonylation
Scientists stumble upon unique transformation that involves breaking an extraordinary number of bonds
-
OpinionThe Nobel prize that got binned
Ferrocene is a classic example of a discovery that was dismissed as a failed experiment
-
ResearchSolar cell concept used to enhance nuclear battery
New device uses a ruthenium dye to absorb beta radiation
-
ResearchBaird’s rule of aromaticity extended to all-metal systems
Aromaticity concept can help scientists understand the properties of metal clusters
-
ResearchSalt crystal grows legs to avoid slippery surface
Sodium chloride’s self-lifting crystallisation has been observed for the first time
-
