Inorganic chemistry – Page 9
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ResearchLargest hollow cage molecule yet made from 1000 atoms
Giant polyoxymetalate cluster contains 240 molybdenum, 740 oxygen and 20 sulfur atoms
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OpinionMarguerite Perey and the last element in nature
Kit Chapman tells the story of the chemist who discovered francium, but was almost denied the credit
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PodcastHexasilabenzene
Brian Clegg discovers what a six-membered silicon ring can tell us about alien life
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ResearchNew bond discovered among spodium elements zinc, cadmium and mercury
Group 12 joins the σ-hole interaction family with spodium bonds
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FeatureMetalloenzyme mastery
There are natural metalloenzymes that make difficult chemistry look easy. James Mitchell Crow talks to the bioinorganic chemists figuring out how to copy them
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ResearchStrange hexagonal form of table salt discovered
Predicted by an evolutionary algorithm, the first hexagonal sodium chloride was made on a diamond surface
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ResearchNew high pressure allotrope of nitrogen solves a chemical mystery
‘Black nitrogen’ shares similarities with other elements in its group on the periodic table – answering the question of why nitrogen normally doesn’t
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ResearchMolecular experiments hope to reveal new physics
Detecting extremely short-lived radium fluoride can explore standard model’s limits
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ResearchNew silicon–silicon bond is a rare example of a π bond without a σ bond
Discovery made in silicon analogue of bicyclobutane
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ResearchShock treatment makes nanocatalysts from metals that are ‘impossible’ to mix
New technique allows nanoparticles to be produced from almost any combination of metals
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ResearchPushing praseodymium past its oxidation limits
Researchers isolate the first molecular species bearing praseodymium(IV), which could find applications in catalysis and new materials
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ResearchCarbon tetrahedron squeezes phosphorus into smallest possible bond angle
Phosphorus manages to stabilise an ultra-strained tetrahedrane’s banana bonds
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ResearchSerendipitous experiment on xenon complex reveals insights into rare gas interaction
Experiment and theory combo gives benchmark for predicting non-covalent complexes
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ResearchFirst ever observation of a neon-containing anion
Showing that a superelectrophilic anion can bind the noble gas crosses hurdle on path to making a stable neon compound
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ResearchNew type of bond is the first to defy actinide contraction trend
Bonds discovered in metallacycles are unique to the 5f elements
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OpinionJimmy Robinson and the atom bomb elements
USAF pilots flew into mushroom clouds to bring back samples that turned out to contain new elements – one of them didn’t make it home
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ResearchA whole new world for barium, including first ever non-ionic barium fluoride
Ligand tames barium, making precursor to first barium–tin and first molecular barium–fluorine bond
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ResearchMetal complexes outperform organics in antimicrobial analysis on crowdsourced compounds
Could this study prompt drug developers to rethink their reluctance to making metal-based pharmaceuticals?
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ResearchTextbook structure rules formulated by Linus Pauling 90 years ago prove unreliable
Just 13% of 5000 oxides found to fulfil all five coordination geometry predictions