Push–pull radical theory finally vindicated after decades of back and forth

Push and pull door sign

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Solvent effect proves that captodative effect really exists after all

After 36 years of contradictory results, scientists have finally found evidence that vindicates a textbook theory predicting so-called push–pull radicals to be more stable than others. Captodative or push–pull radicals contain both electron-withdrawing and electron-donating groups, which seem to makes them more stable than just one of these groups.