Supramolecular chemistry – Page 3
-
Research
First fundamentally new form of adsorption for more than 90 years driven by molecular machines
Unlike physisorption and chemisorption, the newly discovered ‘mechanisorption’ is an active process that can store energy or chemicals
-
Research
Peptide superstructures speed up Michael reaction
A tripeptide that self-assembles into a supramolecular fibres accelerates an asymmetric benchmark reaction by up to 74%
-
Research
Giant molecular cage protects plastic-eating enzyme
Caged protein withstands temperatures much hotter than its usual melting point and becomes 1000 times more resistant to solvents
-
Research
Enantioselective synthesis of elusive chiral nitrogen compounds discovered by chance
An ‘elegant and simple’ way to make nitrogen stereocentres by supramolecular recognition
-
Research
Molecular light switch speeds up tricky cyclodextrin synthesis
Reaction could lower cost of useful macrocycle
-
Research
Gold double helix assembles with DNA-like precision
DNA construction principles create first ever double-helical gold nanocluster assembly
-
Research
Molecular machines talk to living cells for the first time
Artificial molecular motors gently pull on cells’ membrane receptors to trigger a biochemical response
-
Research
Anti-electrostatic halogen bonding shown in solution for the first time
UV-vis spectroscopy and computational analysis explore nature of counterintuitive anionic interaction
-
Opinion
Exploring the potential of nanoarchitectonics
Combining self-assembly techniques from across scientific disciplines could allow us to precisely build any material structure
-
Research
The hole story of how cage molecules could transform synthesis and separation
Chemists are getting to grips with how to put molecules inside other molecules and how this could protect highly reactive reagents and create enzyme-like catalysts
-
Research
258-atom endless knot created with thiazole ligands
Closed loop structure resembles Celtic and Buddhist symbols
-
Research
Intricate supramolecular rosette demonstrates power of cooperative interactions
Rosette assembles inside porphyrin nanoring when all components are present
-
Research
Chemistry Nobel predictions range from organometallic chemistry to DNA synthesis
Crispr is favoured by chemists while publication analysis forecasts winners working on nanocrystals, organometallic chemistry and supramolecular self-assembly
-
Research
Simple lipid networks combine self-assembly, replication, competition and inhibition
Artificial cells have previously lacked the complexity that is distinct to natural life but scientists are edging closer
-
Research
Largest hollow cage molecule yet made from 1000 atoms
Giant polyoxymetalate cluster contains 240 molybdenum, 740 oxygen and 20 sulfur atoms
-
Feature
The function of folding
Can chemists make molecules that fold up as well as proteins? Rachel Brazil talks to the people trying to create foldamers
-
Research
Macrocycles slide freely across carbon nanotubes
Simulations suggest macrocycles show superlubricity at room temperature
-
Research
‘Nanolympiadane’ created from supramolecular building blocks
A self-assembly approach has enabled the synthesis of large interlocked rings including a structure that resembles the Olympic logo
-
Research
Beautiful molecules ring up with a purpose
How Stephen Goldup used his experience in organic synthesis to find a supramolecular niche
-
Research
Molecular machine enables polyrotaxane synthesis with unprecedented precision
Artificial pumps can add up to 10 molecular rings onto polymer dumbbells in a controlled manner