Reactions and synthesis – Page 7
-
Research
Manganese complex behind method for preparing silanols that uses water as an oxidant
By using water as an oxidising agent, the reaction eliminates additional reagents and unwanted side-products
-
Research
Coca plants’ production pathway for cocaine finally unravelled
167-year-old biosynthetic mystery may be solved
-
Research
Radium chelator researchers working to improve targeted cancer therapies
Oak Ridge National Lab team investigate factors underpinnning Ra2+ complex stability and selectivity in attempt to expand the therapeutic utility of radium-223
-
Research
Mystery surrounding metalation reaction’s reagent excess solved
Multiple ‘base-eating’ aggregates discovered in classic directed ortho lithiation
-
Research
Quantum chemical analysis uncovers previously overlooked contributor to carbocation stability trend
Introducing substituents destabilises the parent substrates
-
Research
Gigantic database of building blocks will help artificial intelligence uncover new organocatalysts
Publicly available dataset containing thousands of structures could help chemists develop data-driven reaction optimisation methods for organic synthesis
-
Research
AI beats human experts when it comes to peptide design
Algorithm throws up some counter-intuitive structures in contest
-
Research
Dual use molecular motor can drive or glow
Infrared light can flip molecular machine between rotary motion and photoluminescence
-
Research
Homogeneous catalysis boosted by electrochemical recovery of precious metal complexes
Process can recover metals from industrially important catalysts
-
Research
Fully automated synthesis robot sets new record in stereospecific carbon–carbon bond formation
The robotic platform can make six carbon–carbon bonds without human guidance
-
Research
Chirality-flipping reaction could completely change total synthesis strategies
Photocatalytic reaction that inverts configuration of chiral carbon centres offers new stereochemical editing logic
-
Research
Controversy surrounds corrected chemical structures
Researchers used machine learning-powered NMR prediction to correct improbable structures – but some of their revisions have been challenged
-
Research
AI discovers the best general conditions yet for cross couplings, doubling yields
Algorithm works with robotic experimenter on tricky Suzuki–Miyaura reactions
-
Research
Chemical Turing machine reads molecular tape
Crown ether ratchet reads out molecular strand’s chirality
-
Research
Waste plastics unzipped into useful pieces
Chemical recycling of polyethylene produces feedstock usually obtained from crude oil.
-
Research
Designer catalyst with enzyme-like cavity splits water almost as fast as plants
Catalytic cleft offers new strategy to speed up hydrogen synthesis
-
Research
Amide library created at speed with machine learning and stopped-flow chemistry
Approach used 90% less starting material than continuous flow equivalent
-
Research
Core–shell nanomaterial enhances electrochemical ammonia synthesis
System combines two materials to balance activity and selectivity when reducing nitrogen to ammonia
-
Research
Photochemistry enables safer method for reprocessing plutonium and uranium mixtures
Method bypasses harsh redox reagents while maintaining high separation factors
-
Research
Blood could supply haem centre for biomass-supported catalyst
Haemoglobin-derived catalyst used to reduce nitroarene into aromatic amines