Reactions and synthesis – Page 9
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Forgotten research leads to nickel catalyst that turns CO2 into longer hydrocarbons
Discovery shows that there is life beyond copper for carbon dioxide reduction
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Water works as a monomer in polymer synthesis
Water monomers form direct linkages in polymer backbones when used to synthesise polyethersulfones
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Tripeptide catalyst that creates carbon–carbon bonds works in milk, beer and cell lysates
Study sparks excitement by showing a short-chain peptide can be a potent catalyst in numerous complex environments
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Liquid metal boosts platinum catalyst’s activity 1000 times
Gallium containing single platinum atoms outperforms solid platinum catalysts in electrochemical methanol oxidation
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Carbon fragment’s five atom walk in unprecedented rearrangement reaction
Reaction discovered by accident is a rare case of a room temperature [1,5] carbon shift
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High-pressure compound contains record-breaking 50% hydrogen
Unique hydrogen–methane van der Waals compound is stabilised by nuclear quantum effects
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Carbon monoxide polymerised by unusual thulium sandwich complex
Thulium-mediated oligomerisation of carbon monoxide creates C–H activation catalyst
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Electrocatalytic hydrogen atom transfer could give industrial organic synthesis a boost
The new approach – inspired by decades of energy storage research – is selective, efficient and sustainable
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Discovery of polymorph using ball milling holds promise for drug discovery
Interchangeable switching between three polymorphs demonstrated for the first time
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New family of hollow molecules separates troublesome hydrocarbon mixtures
Meet the cagearenes – 3D frameworks made from aromatic building blocks and methylene groups
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It’s not enough to be 3D and aromatic to be 3D aromatic
Misusing the term 3D aromaticity could put chemists on a slippery slope where the concept loses meaning
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Catalytic alchemy sees device transform one metal so that it behaves like another
Electric charge enables the catalytic ‘speed limit’ for many important reactions to be bypassed
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Bottleable but reactive carbocations are powerful hydride abstractors
Fluorinated trityl cations outperform trityl for hydride abstraction reactions
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Lunar soil shows promise as a catalyst for extraterrestrial photosynthesis
Moon rock could one day be used to accelerate water splitting and carbon dioxide conversion in space to support crewed missions
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Wastewater from battery recycling plants mined for water-splitting catalysts
Electrocatalysts derived from metal pollutants used to generate hydrogen
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Spotlight shone on sped up photochemical reactions in droplets
Light can produce ‘hot spots’ in aerosols that supercharge reaction rates
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Automated carbon-13 NMR structure validation program highlights errors atom-by-atom
Introducing a new measure to quantify molecular structural uncertainty
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Molecular ratchet made from only 26 atoms rotates in one direction
Chiral fuel drives molecular machine’s rotation, mimicking fundamental biological processes
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Light-driven molecular motor made from entirely renewable resources
Green synthetic strategy leads to first light-driven molecular motor from wood biomass
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Origin of water’s DNA-damaging slow electrons discovered
First evidence of intermolecular Coulombic decay in liquid water will allow better modelling of radiation damage in living tissue