Organic chemistry – Page 17
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Research
Alkali cations boost carbon dioxide reduction into feedstock chemical
Discovery enables continuous-flow electrolysers with industrial potential
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Research
AI enantioselectivity predictor set to power computational catalyst screening
Workflow involves mapping a reaction representation onto the activation energy of the stereocontrolling step
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Research
Rapidly alternating polarity stars in selective electrochemical reduction
Rapidly fluctuating AC targets specific carbonyl groups in the presence of several reducible groups
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News
Bots bring chemistry research tools to Twitter
Cheminformatic tool can deliver retrosynthetic analysis
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Research
Tri-agonist molecule designed to stimulate immune system crosstalk
Conjugation chemistry connects three different agonists around a triazine core
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Research
Adding constraints to understand life’s chemical origins
Matt Powner wants to know if there are chemical rules that govern why certain synthetic strategies are embedded in biology
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Research
Chemists reconsider the impact of through-space effects
Through-space electrostatic effects are shown to be dominant in certain radical reactions, where previously through-bond interactions were thought to determine reaction rate
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Research
Supramolecular cage unlocks mild aldehyde reduction strategy
Computational analysis reveals how encapsulation stabilises protonated oxocarbenium ion of furfural, which makes the carbonyl moiety easier to reduce
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Opinion
The active uses of an inert gas
Meeting the many demands for nitrogen in chemical plants requires a fascinating piece of equipment
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Research
Plasmon-assisted click reaction reverses typical relationship between temperature and rate
Decrease in temperature seems to extend lifetime of plasma-induced excited states, which increases probability of reaction occurring
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Research
Programmed cyclodextrin synthesis picks out specific molecule from 117,655 possibilities
Thioacetate orienting group allows for fine-tuned cyclodextrin functionalisation
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Opinion
Five lessons from the career journey of an accidental chemist
Tip and tricks from dilutions to the excellent properties of lab floors
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Research
Neural network based on autocatalytic reaction performs image classification
Click reaction between small organic molecules used to execute a computing task
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Research
Warped nanographene at odds with aromaticity
Scientists discover a π-electron circuit with an odd number of electrons in a polycyclic system
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Research
Coordinative bonding to carbon more nuanced than first thought
New insights from valence bond theory enhance understanding of bonding in carbones
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Research
Double bond metathesis extended to germanium compounds
Partner swapping reaction carried out with digermene compounds, with no need for a catalyst
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Research
Electrochemistry enables new, greener route to aromatic sulfonamides
One-step, metal-free, scalable route synthesises key functional group in drug discovery
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Opinion
Space, energy and synthetic half-reactions
Matching driving forces with intermediates to predict new chemistry