All Reactions and synthesis articles – Page 27
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ResearchNew hypervalent iodine compound is most powerful oxidant in series
2-iodoxybenzoic acid ditriflate can oxidise stubborn hydrocarbons and obstinate polyfluoroalcohols
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Opinion(+)-Microladallene B
A weird structure is enough to spark chemists’ interest, even without any obvious use
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ResearchChiral borane complexes catalyse new synthesis opportunities
N-heterocyclic carbene-borane complexes with a rare stereogenic boron centre demonstrate potential in stereoselective catalysis
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ResearchMagnets that double efficiency of water splitting could help usher in a hydrogen economy
New catalysts based on earth-abundant metals are ‘game-changer’ for hydrogen production
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ResearchCarbon dioxide generated then recycled in polymerisation bicycle
Zinc catalyst links two polymerisation reactions to grow block copolymer
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ResearchBaran and Blackmond team up to wave farewell to tough ether syntheses
Oxidative decarboxylation produces carbocations that greatly speed up hindered ether production
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ResearchBrown ring molecule defies the very definition of oxidation state
Classic nitrate test compound isolated for the first time challenges chemistry governing body’s ideas on oxidation state
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ResearchCan catalysis save us from our CO2 problem?
We need to start seeing carbon dioxide as as a valuable raw material to make chemicals, fuels and even food
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Opinion‘Coffee machine’ synthesiser’s first steps
Cartridge-based machine enables non-experts to make heterocycles
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ResearchC–H fluoroalkylation tackles plastic waste
Photocatalytic method that upcycles aromatic polymers could breathe new life into rubbish
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ResearchMinty-fresh solvent for sustainable cross-couplings
Eucalyptol could replace diethyl ether, DMF, THF and toluene in many synthetic reactions
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ResearchQuantum mechanical mechanism behind 100-year-old textbook reaction revealed
Study challenges established understanding of Michael addition as it uncovers Pauli repulsion’s key role in halogen catalysis
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ResearchNon-natural system uses covalent base-pairing to transfer information
Template-directed process that replicates non-biological molecules is step towards using evolution to explore chemical space
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NewsInternational Space Station experiments will search for key to soot-free flames
Microgravity research could help to burn fuels more cleanly and cut soot’s contribution to ill health and climate change
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ResearchNew compounds make dissolving gold simpler and safer
Polypseudohalogen-based ionic liquid offers innovative way to recycle electronics
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ResearchDirecting group ‘dance’ decorates heterocycles
Reaction that multi-functionalises nitrogen heteroaromatics using a movable directing group has already attracted the attention of industrial chemists
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ResearchSurprising radical mechanisms of antioxidant polysulfides
Tetrasulfide prevents oxidation of petroleum products through radical reactions
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ResearchConverting waste plastic bottles into jet fuel
Simple three-step process generates minimal waste and diverts plastic from landfill
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ResearchFirst radial-conjugated aromatic that does the twist
Figure-of-eight shaped molecule is the first with a radial π-electron system
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